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Ty⬝D⬝Bol Automatic Rust Toilet Cleaner-02/09/2022
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Toilet bowl cleanerStructure such as solid, liquid, aerosol etc.
Form: solidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 13, 20244044 Park Avenue
Saint Louis MO 63110
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 068081-81-2 -- 10.0 -- -- -- -- 068140-00-1 -- 21.0 -- -- -- -- 025265-71-8 -- -- -- -- -- 000119-36-8 -- 1.8 -- -- -- -- 000497-19-8 -- Xi -- -- -- -- 009004-32-4 -- 5.0 -- -- -- -- 000527-07-1 -- -- -- -- -- 007775-14-6 -- 14.56 Xn -- -- -- -- 007681-57-4 -- Xn, Xi -- -- -- -- 007757-82-6 -- -- -- -- -- 007757-83-7 -- -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
Chemical Function Purpose served by this chemical.Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)C10-16 Alkylbenzene Sulfonic Acid
Surfactant
068081-81-2
268-356-110.0 No -- -- -- No No Cocamide MEA
Surfactant
068140-00-1
268-770-221.0 No -- -- -- No No Dipropylene glycol
Solvent
025265-71-8
246-770-3-- No -- -- -- No No Methyl salicylate
Fragrance
000119-36-8
204-317-71.8 No H302, H318 P280, P305+P351+P338, P310, P264, P270, P501 No No Sodium carbonate
Reducing agent
000497-19-8
207-838-8-- No H319 P264, P280, P305+P351+P338, P337+313 No No Sodium Carboxymethyl Cellulose
Binder
009004-32-4
-5.0 No -- -- -- Yes No Sodium gluconate
Chelating Agent
000527-07-1
208-407-7-- No -- -- -- No No Sodium hydrosulfite
Reducing agent
007775-14-6
231-890-014.56 No H251, H302, EUH031 P235+P410, P301+P312, P302+P352, P420 No No Sodium metabisulfite
Reducing agent
007681-57-4
231-673-0-- No H302, H318, EUH031 P264, P280, P330, P305+P351+P338, P310 No No Sodium sulfate
Viscosity Adjuster
007757-82-6
231-820-9-- No -- P262 -- No No Sodium sulfite
Reducing agent
007757-83-7
231-821-4-- No -- -- -- No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H251 : Self-heating; may catch fireH302 : Harmful if swallowedH318 : Causes serious eye damageH319 : Causes serious eye irritationEUH031 : Contact with acids liberates toxic gas
- P262 : Do not get in eyes, on skin, or on clothingP264 : Wash … thoroughly after handlingP270 : Do not eat, drink or smoke when using this productP280 : Wear protective gloves/protective clothing/eye protection/face protectionP235+P410 : Keep cool. Protect from sunlightP310 : Immediately call a POISON CENTER or doctor/physicianP330 : Rinse mouthP301+P312 : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP302+P352 : IF ON SKIN: Wash with soap and waterP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP420 : Store away from other materialsP501 : Dispose of contents/container to
- GHS02 : FlammableGHS05 : CorrosiveGHS07 : Irritant
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :February 09, 2022 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING3* 0 0 -
SVHC declaration
Warning: This product contains Substances of Very High Concern (SVHC).
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Warnings
Hazard Statements
Danger. Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May damage fertility or the unborn child.
Precautionary Statements
General
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
Prevention
Wear protective gloves/protective clothing/eye protection/face protection. Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product.
Response
IF exposed or concerned: Get medical advice/attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor.
IF ON SKIN: Wash with plenty of water and soap. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse.
IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell. Rinse mouth.
Storage
Store locked up.
Disposal
Dispose of contents/container to an approved waste disposal plant. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
Danger. Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May damage fertility or the unborn child.
Potential Health Effect
Eye Contact: Specific test data for the substance or mixture is not available. Causes serious eye damage. (based on components). Severely irritating to eyes. May cause burns. May cause irreversible damage to eyes.
Skin Contact: Specific test data for the substance or mixture is not available. Causes skin irritation. (based on components).
Inhalation: Specific test data for the substance or mixture is not available. May cause irritation of respiratory tract.
Ingestion: Specific test data for the substance or mixture is not available. Harmful if swallowed. (based on components).
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. -
Chronic health effects
From SDS:
No data. -
Carcinogenicity
No information available. -
Handling information
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Remove contaminated clothing and shoes. Take off contaminated clothing and wash before reuse. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Store locked up. -
Disposal information
Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation. Do not reuse empty containers. -
California Prop. 65 Warning
This product does not contain any Proposition 65 chemicals.
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First Aid
Eye Contact: Get immediate medical advice/attention. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area.Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical attention if irritation develops and persists.Inhalation: Remove to fresh air. Get medical attention immediately if symptoms occur.this safety data sheet to the doctor in attendance. Immediate medical attention is required.Ingestion: Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a physician.
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